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Gradient enhanced NMR is a method for obtaining high resolution nuclear magnetic resonance spectra without the need for ''phase cycling''. Gradient methodology is used extensively for two purposes, either rephasing (selection) or dephasing (elimination) of a particular magnetization transfer pathway. It includes the application of magnetic field gradient pulses to select specific coherences. By using actively shielded gradients, a gradient pulse is applied during the evolution period of the selected coherence to dephase the transverse magnetization and another gradient pulse refocuses the desired coherences remaining during the acquisition period. ==Advantages== *Significant reduction in measuring time *Reduced T1 artifacts *Elimination of phase cycling and difference methods *Possibility for three and four-quantum editing *The ability to detect resonances at the same chemical shift as a strong solvent resonance 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Gradient enhanced NMR spectroscopy」の詳細全文を読む スポンサード リンク
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